T/GZNFS 001.2-2019 Chemical Analysis Methods for Tungsten Slag - Part 2: Determination of Molybdenum Content
T/GZNFS 001.2-2019
Basic Information
Scope
Scope: This part specifies the method for determining the molybdenum content in alkali slag produced during the alkali decomposition process of ammonium paratungstate. This part is applicable to the determination of molybdenum content in alkali slag produced during the alkali decomposition process of ammonium paratungstate. The determination range (mass fraction): 0.10% to 2.00%; Main technical content: The sample is melted with sodium peroxide, extracted with water, and the molybdenum is separated from most of the iron, manganese, copper, bismuth, and calcium. The tungsten is masked with citric acid, and with copper salt as a catalyst, the molybdenum is reduced to the pentavalent state in a dilute sulfuric acid solution. Then, the molybdenum reacts with thiocyanate to form an orange-red complex, and its absorbance is measured at a wavelength of 460 nm using a spectrophotometer to calculate the molybdenum content.